Publications | Etzoldlab

2020

Porous graphite as stationary phase for the chromatographic separation of polymer additives – determination of adsorption capability by Raman spectroscopy and physisorption , D. Kot, M Zou, K. Brunnengräber, J.-H. Arndt, T. Macko; B.J.M. Etzold and R. Brüll, J. Chromatogr. A, accepted

Mechanistic Study on the Selective Oxidation of Acrolein to Acrylic Acid concerning the Role of Water , S. Knoche, M. Heid, N. Gora, D. Ohlig, A. Drochner, B.J.M. Etzold and H. Vogel, ChemCatChem, 12, 1-17

Methanol Oxidative Dehydrogenation and Dehydration on Carbon Nanotubes: Active Sites and Basic Reaction Kinetics , P.Q. Yan, X.F. Zhang, F. Herold, F. Li, X. Dai, T.L. Cao, B.J.M Etzold and W. Qi, Catal. Sci. & Technol., accepted

Carbide-derived niobium pentoxide with an enhanced charge storage capacity for use as a lithium-ion battery electrode , Ö. Budak, M. Geißler, D. Becker, A. Kruth, A. Quade, R. Haberkorn, G. Kickelbick, B.J.M. Etzold and V. Presser, ACS Appl. Energy Mater., accepted

Cathodic activated stainless steel mesh as a highly active electrocatalyst for the oxygen evolution reaction with self-healing possibility   , G.-R. Zhang, L.-L. Shen, P. Schmatz, K. Krois and B.J.M. Etzold, J. Energy Chem., 49, 153-160

Paper‐Based Microfluidics for Electrochemical Applications , L.-L. Shen, G.-R. Zhang and B.J.M. Etzold, ChemElectroChem, 7, 10-30

2019

Combining autoclave and LCWM reactor studies to shed light on the kinetics of glucose oxidation catalyzed by doped molybdenum-based heteropoly acids , D. Voß, S. Ponce, S. Wesinger, B.J.M. Etzold and J. Albert, RSC Adv., 9, 29347

Paper-based Microfluidic Aluminum-Air Batteries: Toward Next-Generation Miniaturized Power Supply , L.-L. Shen, G.-R. Zhang, M. Biesalski and B.J.M. Etzold , Lab Chip, 19, 3438-3447

The Effect of Ionic Liquid Modification on the ORR Performance and Degradation Mechanism of Trimetallic PtNiMo/C Catalysts , M. George, G.-R. Zhang, N. Schmitt, K. Brunnengräber, D.J.S. Sandbeck, K.J.J. Mayrhofer, S. Cherevko and B.J.M. Etzold, ACS Catal., 9, 8682

Oxidative dehydrogenation on nanocarbon: Effect of heteroatom doping , W. Li, C. Wang, F. Herold, B.J.M. Etzold, D.S. Su and W. Qi, Appl. Catal. B, 258, 118982

Investigation of the phase equilibria of CO2/CH3OH/H2O and CO2/CH3OH/H2O/H2 mixtures , K. Vogel, E. Hocke, L. Beisswenger, A. Drochner, B.J.M. Etzold and H. Vogel, Chem. Eng. Technol., 42, 2386-2392

Activated carbon in the 3rd dimension – 3D printing of a tuned porous carbon , H. Steldinger, A. Esposito, K. Brunnengräber, J. Gläsel and B.J.M. Etzold, Adv. Sci, 1901340

Mechanistic study on the selective oxidation of acrolein to acrylic acid: -Identification of the rate-limiting step via perdeuterated acrolein , S. Knoche, M. Heid, N. Gora, D. Ohlig, A. Drochner, C. Hess, B.J.M. Etzold and H. Vogel, ChemCatChem, 11, 3242-3252

Simulative Approach for Linking Electrode and Electrolyte Properties to Supercapacitor Performance , K. Krois, L. Hüfner, J. Gläsel and B.J.M. Etzold, Chem. Ing. Tech., 91, 889-899

Insights into the redox kinetics of vanadium substituted heteropoly acids through liquid core waveguide membrane microreactor studies , S. Ponce, M. Trabold, A. Drochner, J. Albert and B.J.M. Etzold, Chem. Eng. J., 369, 443-250

Improving control of carbide-derived carbon microstructure by immobilization of a transition-metal catalyst within the shell of carbide/carbon core–shell structures , T. Ariyanto, J. Gläsel, A. Kern, G.-R. Zhang and B.J.M. Etzold, Beilstein J. Nanotechnol., 10, 419-427

Combined Computational and Experimental Study on the Influence of Surface Chemistry of Carbon-Based Electrodes on Electrode–Electrolyte Interactions in Supercapacitors , S. Schweizer, J. Landwehr, B.J.M. Etzold, R.H. Meißner, M.Amkreutz, P. Schiffels and J.-R. Hill, J. Phys. Chem. C., 123, 2716-2727

Towards best practices for improving paper-based microfluidic fuel cells , L.-L. Shen, G.-R. Zhang, T. Venter, M. Biesalski and B.J.M Etzold, Electrochim. Acta, 298, 389-399

2018

An Optical Microreactor Enabling In Situ Spectroscopy Combined with Fast Gas-Liquid Mass Transfer , S. Ponce, H. Christians, A. Drochner and B.J.M. Etzold, Chem. Ing. Tech., 90, 1855-1863

Tuning the Electrocatalytic Performance of Ionic Liquid Modified Pt Catalysts for Oxygen Reduction Reaction via Cationic Chain Engineering , G.-R. Zhang, T. Wolker, D.J.S. Sandbeck, M. Munoz, K.J.J. Mayrhofer, S.Cherevko and B.J.M. Etzold, ACS Catal., 8, 8244–8254

Stable Immobilization of Size‐Controlled Bimetallic Nanoparticles in Photonic Crystal Fiber Microreactor , S. Ponce, M. Munoz, A. M. Cubillas, T. G. Euser, G.‐R. Zhang, P. St. J. Russell, P. Wasserscheid and B.J.M. Etzold, Chem. Ing. Tech., 90, 653-659

Introducing Sulphur Surface Groups in Microporous Carbons: A mechanistic study on carbide derived carbons , J. Landwehr, H. Steldinger and B.J.M. Etzold, Catal. Today, 301, 191-195

Aqueous-phase reforming of alcohols with three carbon atoms on carbon-supported Pt , L.I. Godina, A.V. Tokarev, I.L. Simakova, P. Mäki-Arvela, E. Kortesmäki, J. Gläsel, L. Kronberg, B.J.M. Etzold and D. Yu. Murzin, Catalysis Today, 301, 78-89

Editoral special issue CarboCat-VII , B.J.M. Etzold and D. Begin, Catal. Today, 301, 1

Improved electrochemical performance of Fe-N-C catalysts through ionic liquid modification in alkaline media , I. Martinaiou, T. Wolker, A. Shahraeia, G.-R. Zhang, A. Janßen, S. Wagner, N. Weidler, R.W. Stark, B.J.M. Etzold and U.I. Kramm, Journal of Power Sources, 375, 222-232

2017

Heterogeneously Catalyzed Hydrogenation of Supercritical CO2 to Methanol , B. Kommoß, S. Klemenz, F. Schmitt, E. Hocke, K. Vogel, A. Drochner, B. Albert, B. J.M. Etzold and H. G. Vogel, Chem. Eng. Technol., 40, 1907-1915

Activity Hysteresis during Cyclic Temperature-Programmed Reactions in the Partial Oxidation of Acrolein to Acrylic Acid , S. Knoche, M. Heid, N. Gora, D. Ohlig, A. Drochner, H. Vogel and B.J.M. Etzold, Chem. Eng. Technol., 40, 2084-2095

Characterization of V–Mo–W Mixed Oxide Catalyst Surface Species by 51V Solid-State Dynamic Nuclear Polarization NMR , A.S.L. Thankamony, S. Knoche, S. Bothe, A. Drochner, A.P. Jagtap, S.Th. Sigurdsson, H. Vogel, B.J.M. Etzold, T. Gutmann and G. Buntkowsky , J. Phys. Chem. C, 121, 20857–20864

Modifier-Free Microfluidic Electrochemical Sensor for Heavy-Metal Detection , L.-L. Shen, G.-R. Zhang, W. Li, M. Biesalski and B.J.M. Etzold, ACS Omega, 2, 4593–4603

Carbide-derived carbon with hollow core structure and its performance as catalyst support for methanol electro-oxidation , T. Ariyanto, A. Kern, B.J.M. Etzold and G.-R. Zhang, Electrochemistry Communications, 82, 12-15

Polymer-based spherical activated carbon as catalytic support for hydrodechlorination reactions , M. Munoz, V. Kolb, A. Lamolda, Z.M. de Pedro, A. Modrow, B.J.M. Etzold, J.J. Rodriguez and J.A. Casas, Appl. Catal. B, 218, 498-505

Carbon structure in nanodiamonds elucidated from Raman spectroscopy , V.I. Korepanov, H. Hamaguchi, E. Osawa, V, Ermolenkov, I.K. Lednev, B.J.M. Etzold, O. Levinson, B. Zousman and C. Prakash, Carbon, 121, 322-329

Molecular Modeling of Microporous Structures of Carbide-Derived Carbon-Based Supercapacitors , S. Schweizer, R. Meißner, M. Amkreutz, K. Thiel, P. Schiffels, J. Landwehr, B.J.M. Etzold and J.-R. Hill, J. Phys. Chem. C, 121, 7221–7231

Dynamics of Bulk Oxygen in the Selective Oxidation of Acrolein , M. Heid, S.F. Knoche, N.S.A. Gora, D. Ohlig, A. Drochner, B.J.M. Etzold and H.G. Vogel, ChemCatChem, 9, 2390–2398

Controlled synthesis of core-shell carbide-derived carbons through in situ generated chlorine , T. Ariyanto, G.-R. Zhang, F. Riyahi, J. Gläsel and B.J.M. Etzold, Carbon, 115, 422–429

Photochemistry in soft-glass single-ring hollow-core photonic crystal fiber , A. M Cubillas, X. Jiang, T. Godfried Euser, N. Taccardi, B.J.M. Etzold, P. Wasserscheid and P. Russell, Analyst, 142, 925-929

Exploring the role of the catalytic support sorption capacity on the hydrodechlorination kinetics by the use of carbide-derived carbons , M. Munoz, G.-R. Zhang and B.J.M. Etzold, Appl. Catal. B, 203, 591–598

2016

Vanadium pentoxide / carbide-derived carbon core-shell hybrid particles for high performance electrochemical energy storage , M. Zeiger, T. Ariyanto, B. Krüner, S. Fleischmann, N.J. Peter, B.J.M. Etzold and V. Presser, J. Mater. Chem. A, 4, 18899-18909

Controlled synthesis of PVP-based carbon supported Ru nanoparticles: synthesis approaches, characterization, capping agent removal and catalytic behavior , I. Simakova, Y. Demidova, J. Glaesel, E. Murzina, T. Schubert, I. Prosvirin, B.J.M. Etzold and D. Murzin , Catal. Sci. Technol., 6, 8490-8504

Size-controlled PtNi nanoparticles as highly efficient catalyst for hydrodechlorination reactions , M. Munoz, S. Ponce, G.-R. Zhang and B.J.M. Etzold, Appl. Catal. B. 192, 1-7.

Improved synthesis and hydrothermal stability of Pt/C catalysts based on size-controlled nanoparticles , J. Lemus, J. Bedia, L. Calvo, I. Simakova, D. Murzin, B.J.M. Etzold, J.J. Rodriguez and M.A. Gilarranz, Catal. Sci. Technol. 6, 5196-5206.

Thermal and electrical conductivity of amorphous and graphitized carbide-derived carbon monoliths , A.M. Kern, B. Zierath, T. Fey and B.J.M. Etzold, Chem. Eng. Technol. 39, 1121-1129.

Boosting the activity in SILP catalyzed hydroformylation via surface functionalization of the carbon support , A. Weiß, M. Munoz, A. Haas, F. H. Rietzler, H-P. Steinrück, M. Haumann, P. Wasserscheid, and B. J.M. Etzold, ACS Catal. 6, 2280-2286.

Adsorption of nickel ions on oxygen functionalized carbons , A.M. Kern, B. Zierath, T. Fey and B.J.M. Etzold, Chem. Eng. Technol. 39, 715-722.

Ionic liquids in electrocatalysis , G.-R. Zhang, and B.J.M. Etzold, J. Energ. Chem. 25, 199–207.

Polymer-based spherical activated carbon as easy-to-handle catalyst support for hydrogenation reactions , H. Klefer, M. Munoz, A. Modrow, B. Böhringer, P. Wasserscheid, and B.J.M. Etzold, Chem. Eng. Tech. 39, 276-284.

Deducing kinetic constants for the hydrodechlorination of 4-chlorophenol using high adsorption capacity catalysts , M. Munoz, M. Kaspereit, and B.J.M. Etzold, Chem. Eng. J. 285, 228-235.

Producing High Quality Carbide-Derived Carbon from Low Quality Byproducts Stemming from SiC Production , T. Ariyanto, A.M. Laziz, J. Gläsel, G.-R. Zhang, J. Garbes and B.J.M. Etzold, Chem. Eng. J. 283, 676.

2015

Determination of vapor pressure and thermal decomposition using thermogravimetrical analysis , F. Heym, W. Korth, B.J.M. Etzold, C. Kern and Andreas Jess, Thermochimica Acta 622, 9-17.

Accelerating Oxygen Reduction Catalysts through Preventing Poisoning with Non-Reactive Species by Using Hydrophobic Ionic Liquids , G.-R. Zhang, M. Munoz, and B.J.M. Etzold, Angew. Chem. Int. Ed. 55, 2257-2261.

Mesoporous and Graphitic Carbide-Derived Carbons as Selective and Stable Catalysts for the Dehydrogenation Reaction , J. Gläsel, J. Diao, Z. Feng, M. Hilgart, T. Wolker, D.S. Su and B.J.M. Etzold, Chem. Mater. 27, 5719.

Synthesis of Carbon Core–Shell Pore Structures and their Performance as Supercapacitors , T. Ariyanto, B. Dyatkin, G.-R. Zhang, A. Kern, Y. Gogotsi and B.J.M. Etzold, Microporous and Mesoporous Mater. 218, 130-136.

Boosting Performance of Low Temperature Fuel Cell Catalysts by Subtle Ionic Liquid Modification , G.-R. Zhang, M. Munoz, B.J.M. Etzold, ACS Appl. Mater. Interfaces 7, 3562- 3570.

Preparation of carbide- derived carbon supported platinum catalysts , B. Hasse, J. Gläsel, A.M. Kern, D.Yu. Murzin and B.J.M. Etzold, Catal. Today 249, 30-37.

A feasible way to remove the heat during adsorptive methane storage , S. Gütlein, C. Burkard, J. Zeilinger, M. Niedermaier, M. Klumpp, V. Kolb, A. Jess and B.J.M. Etzold, Environ. Sci. Technol. 49, 672-678.

2014

Layer-by-Layer Oxidation for Decreasing the Size of Detonation Nanodiamond , B.J.M. Etzold, I. Neitzel, M. Kett, F. Strobl, V.N. Mochalin and Y. Gogotsi, Chem. Mater. 26, 3479- 3484

In-situ Heterogeneous Catalysis Monitoring in a Hollow-Core Photonic Crystal Fiber Microflow Reactor , A.M. Cubillas, M. Schmidt, T.G. Euser, N. Taccardi, S. Unterkofler, P. St.J Russell, P. Wasserscheid, and B.J.M. Etzold, Adv. Mat. Interfaces 1300093.

Comparing different synthesis procedures for carbide-derived carbon based structured catalyst supports , T. Knorr, A. Schwarz, and B.J.M. Etzold, Chem. Eng. Technol. 37, 453-461.

Aqueous-phase reforming of xylitol over Pt/C and Pt/TiC-CDC catalysts: catalyst characterization and catalytic performance , A.V. Kirilin, B. Hasse, A.V. Tokarev, L.M. Kustov, G.N. Baeva, G.O. Bragina, A.Y. Stakheev, A.R. Rautio, T. Salmi, B.J.M. Etzold, J.P. Mikkola, and D.Y. Murzin, Cat. Sci. Technol. 4, 387-401.

An advanced method to manufacture hierarchically structured carbide-derived carbon monoliths , T. Fey, B. Zierath, A. Kern, P. Greil, and B.J.M. Etzold, Carbon 70, 30-37.

2013

High selectivity of TiC-CDC for CO2/N2 separation , A. Silvestre-Albero, S. Rico-Frances, F. Rodriguez-Reinoso, A.M. Kern, M. Klumpp, B.J.M. Etzold, and J. Silvestre-Albero, Carbon 59, 221-228.

“Chemical and (Photo)-Catalytical Transformations in Photonic Crystal Fibers” , M. Schmidt, A.M. Cubillas, N. Taccardi, T.G. Euser, T. Cremer, F. Maier, H.-P. Steinrück, P. St.J. Russell, P. Wasserscheid, and B.J.M. Etzold, ChemCatChem 5, 641-650.

“Photonic crystal fibres for chemical sensing and photochemistry” , A.M. Cubillas, S. Unterkofler, T.G. Euser, B.J.M. Etzold, A.C. Jones, P.J. Sadler, P. Wasserscheid, and P. St.J. Russell, , Chem. Soc. Rev. 42, 8629-8648.

2012

Titanium carbide-derived carbon as a novel support for platinum catalysts in direct methanol fuel cell application , A. Schlange, A.R. dos Santos, B. Hasse, B.J.M. Etzold, U. Kunz, and T. Turek, J. Power Sources 199, 22-28.

Recommendations for the Production of Silicon Carbide-derived Carbon Based on Intrinsic Kinetic Data , T. Knorr, F. Strobl, F. Glenk, and B.J.M. Etzold, Chem. Eng. Technol. 35, 1495-1503.

Shrinking core like fluid solid reactions- A dispersion model accounting for fluid phase volume change and solid phase particle size distributions , T. Knorr, M. Kaiser, F. Glenk, and B.J.M. Etzold, Chem. Eng. Sci. 69, 492-502.

Process specific catalyst supports – Selective electron beam melted cellular metal structures coated with microporous carbon , T. Knorr, P. Heinl, J. Schwerdtfeger, C. Körner, R.F. Singer, and B.J.M. Etzold, Chem. Eng. J. 181-182, 725-733.

Ultra-Low Concentration Monitoring of Catalytic Reactions in Photonic Crystal Fiber , A.M. Cubillas, M. Schmidt, M. Scharrer, T.G. Euser, B.J.M. Etzold, N. Taccardi, P. Wasserscheid, and P. St.J. Russell, Chem. Eur. J. 18, 1586-1590.

2011

Fast production of monolithic carbide-derived carbons with secondary porosity produced by chlorination of carbides containing a free metal phase , M. Schmirler, T. Knorr, T. Fey, A. Lynen, P. Greil, and B.J.M. Etzold, Carbon 49, 4359-4367.

In-situ thermal activation of carbide-derived carbon , M. Schmirler, F. Glenk, and B.J.M. Etzold, Carbon 49, 3679-3686.

Covalent Incorporation of Aminated Nanodiamond into an Epoxy Polymer Network , V.N. Mochalin, I. Neitzel, B.J.M. Etzold, A. Peterson, G. Palmese, and Y. Gogotsi, ACS Nano 5, 7494-7502.

Analysis of evaporation and thermal decomposition of ionic liquids by thermogravimetrical analysis at ambient pressure and high vacuum , F. Heym, B.J.M. Etzold, C. Kern, and A. Jess, Green Chem. 13, 1453-1466.

2010

Vapor Pressure of Water in Mixtures with Hydrophilic Ionic Liquids – A Contribution to the Design of Processes for Drying of Gases by Absorption in Ionic Liquids , F. Heym, J. Haber, W. Korth, B.J.M. Etzold, and A. Jess, Chem. Eng. Technol. 33, 1625-1634.

An improved method to measure the rate of vaporisation and thermal decomposition of high boiling organic and ionic liquids by thermogravimetrical analysis , F. Heym, B.J.M. Etzold, C. Kern, and A. Jess, Phys. Chem. Chem. Phys. 12, 12089-12100.

Synthese mikroporöser Kohlenstoffschäume für katalytische Anwendungen , F. Glenk, M. Schirmer, S. Gütlein, and B. Etzold, Chem. Ing. Tech. 82, 897-903.

Synthesis of microporous carbon foams as catalyst supports , F. Glenk, T. Knorr, M. Schirmer, S. Gütlein, and B. Etzold, Chem. Eng. Technol. 33, 698-703.

Chlorination of titanium carbide for the processing of nanoporous carbon: A kinetic study , P. Becker, F. Glenk, M. Kormann, N. Popovska, and B.J.M. Etzold, Chem. Eng. J. 159, 236–241.

2009

Epimerisation of Menthol-Diastereomers: Kinetic Studies for the Heterogeneously Catalysed Menthol Production , B. Etzold, A. Jess, and M. Nobis, Catal. Today 140, 30- 36.

2008

Kinetic study of the asymmetric hydrogenation of methyl acetoacetate in the presence of a ruthenium binaphthophosphepine complex , E. Öchsner, B. Etzold, K. Junge, M. Beller, and P. Wasserscheid, Adv. Synth. Catal. 351, 235-245.

Epimerisation of Menthol Stereoisomers Part 2: Improvement by the use of a continuous presaturated one liquid flow reactor , B. Etzold, and A. Jess, Chemistry Today 26, 13- 18.

Epimerisation of Menthol Stereoisomers Part 1: Studies on the Intrinsic Kinetics , B. Etzold, and A. Jess, Chemistry Today 26, 21-24.

“Heterogeneously Catalysed Epimerisation of Menthol Stereoisomers an Instructive Example to Account for Diffusion Limitations in Complex Reaction Networks” , B. Etzold, and A. Jess, Chem. Eng. Technol. 31, 1282-1289.

2007

Solid catalyst with ionic liquid layer (SCILL) – a new concept to improve selectivity illustrated by hydrogenation of cyclooctadiene , U. Kernchen, B. Etzold, W. Korth, and A. Jess, Chem. Eng. Technol. 30, 985-994.

“Verbesserung der Selektivität fester Katalysatoren durch die Beschichtung mit ionischen Flüssigkeiten – Untersuchungen am Beispiel der Hydrierung von Cyclooctadien” , U. Kernchen, B. Etzold, W. Korth, and A. Jess, Chem. Ing. Tech. 79, 807-819.